Crystal structures, syntheses, and spectroscopic and electrochemical measurements of two push–pull chromophores: 2-[4-(dimethylamino)benzylidene]-1H-indene-1,3(2H)-dione and (E)-2-{3-[4-(dimethylamino)phenyl]allylidene}-1H-indene-1,3(2H)-dione
نویسندگان
چکیده
منابع مشابه
2-(4-Methoxyphenyl)-1H-indene
Excluding four H atoms, the molecule of the title compound, C(16)H(14)O, is almost planar, with an r.m.s. deviation of 0.0801 (2) Å. Due to p-π conjugation, the lengths of the two single bonds attached to the O atom are significantly different.
متن کاملCrystal structure of 2-hydroxy-2-(2-oxocycloheptyl)-2,3-dihydro-1H-indene-1,3-dione
In the title compound, C16H16O4, the five-membered ring of the indene-1,3-dione unit adopts a twist conformation, whereas the seven-membered ring adopts a twist-chair conformation. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, weak C-H⋯O hydrogen bonds and π-π stacking [centroid-to-centroid distance = 3.7373 (8) Å] into a three-dimensional supra-molecular architecture.
متن کاملCrystal structure of 2-(5-bromo-2-hydroxybenzylidene)-2,3-dihydro-1H-indene-1,3-dione
The title mol-ecule, C16H9BrO3, deviates slightly from planarity. The benzene ring makes a dihedral angle of 1.02 (9)° with the plane defined by the five-membered ring of the indandione moiety. The latter exhibits a minute twist indicated by the dihedral angle of 0.47 (9)° between the planes of the five- and six-membered rings. An intra-molecular C-H⋯O hydrogen bond between the attached benzene...
متن کاملEthyl 2-(4-methylbenzoyl)-2,3-dihydro-1H-indene-2-carboxylate
The title compound, C20H20O3, contains two fused rings with a quaternary carbon centre connecting p-toluoyl and eth-oxy-carbonyl groups. The dihedral angle between the fused benzene ring and the three-C-atom plane (derived from O=C-C-C=O) is 82.5 (4)°, whereas the dihedral angle between the planes of the benzene rings is 53.4 (2)°. In the crystal, molecules are linked via C-H⋯Oester hydrogen bo...
متن کاملrac-2-Hydroxy-2-(2-oxocyclopentyl)-1H-indene-1,3(2H)-dione
In the title compound, C(14)H(12)O(4), the indene unit is essentially planar [r.m.s. deviation = 0.0309 (1) Å] and the cyclo-penta-none ring adopts a twist form. In the crystal, mol-ecules are joined via pairs of O-H⋯O hydrogen bonds into centrosymmetric dimers.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications
سال: 2019
ISSN: 2056-9890
DOI: 10.1107/s205698901901329x